Interrupting capacity is the headline here: 187 kA at 240 V AC, 121 kA at 415 V, 76 kA at 440 V, and 17 kA at both 500 V and 690 V. Thermal derating is mild: it holds 100 A flat from 40 °C through 50 °C, then drops to 98 A at 55 °C, 96 A at 60 °C, 94 A at 65 °C, and 91 A at 70 °C. That curve means you don't lose rating in a warm panel until you're past 50 °C ambient — useful when the breaker sits above heat-producing gear in a sealed enclosure.
The shunt trip order code is 3VA9688-0BL33 — that's the add-on you need if you're wiring an emergency-stop or remote-trip circuit.
For an independent-trader question: this 3VA1132-6GF46-0KF0 will not drop into a panel wired for the 3VA1010-2ED32-0JA0 without checking the mounting footprint and bus-bar spacing — the frame sizes differ (the 3VA1010 is a smaller frame). The auxiliary and shunt-trip wiring may line up, but the physical cutout and lug centers are not guaranteed to match. Best to compare panel cutout dimensions before assuming a swap.